Monday, March 10, 2025

 

Year of Quantum Science & Technology

Pioneers of Quantum Theoretical Physics

 Part 1


IYQ25 coincides with the 100th anniversary of the birth of modern quantum mechanics — the theory that describes the behaviour of matter and energy at atomic and subatomic scales and has made possible many of the world’s most important technologies. Over the past century, quantum theory has become foundational to physics, chemistry, engineering, and biology and has revolutionized modern electronics and global telecommunications. Inventions like the transistor, lasers, rare-earth magnets, and LEDs — technologies that brought the internet, computers, solar cells, MRI, and global navigation into fruition — all exist because of quantum mechanics.


Two of the greatest pioneers of quantum science

 

UNESCO has proclaimed 2025 as the International Year of Quantum Science and Technology (IYQ). This year-long, worldwide initiative will celebrate the contributions of quantum science to technological progress over the past century, raise global awareness of its importance to sustainable development in the 21st century, and ensure that all nations have access to quantum education and opportunities. In celebration of IYQ25, this series of articles focuses on the key personalities of quantum theoretical physics and their work – ten of the greatest, from Planck to Feynman.

 

Prelude

Dedicated to the promotion of both science and scientific culture, the UNESCO has, over the years, focused on some key themes/events and designated the corresponding year for special attention and international observance. Here is a representative list:

  • 2005 – International Year of Physics, celebrating the centennial of Einstein’s ‘Miracle Year’ 1905 marking his groundbreaking publications.
  • 2009 – International Year of Astronomy, marking the 400th anniversary of Galileo’s first telescopic observations.
  • 2011 – International Year of Chemistry, celebrating the achievements of chemistry and its contributions to humankind.
  • 2022 – International Year of Basic Sciences for Sustainable Development.

This year, 2025 has also received similar attention – as the International Year of Quantum Science and Technology.

IYQ25

The International Year of Quantum Science and Technology (IYQ) 2025 has been proclaimed by the United Nations to commemorate the centennial of quantum mechanics and to emphasize its significance in modern science and technology. The primary objectives of IYQ 2025 include:

1. Increase Public Awareness: Highlight the importance of quantum science and its applications in everyday life, aiming to educate the public about its foundational role in various technologies.

2. Promote Education and Diversity: Encourage educational initiatives to inspire young individuals, especially women and those from developing countries, to pursue studies and careers in quantum science, fostering inclusivity and diversity in the field.

3. Support Sustainable Development: Demonstrate how quantum technologies can contribute to achieving the United Nations' Sustainable Development Goals, particularly in areas like energy, environment, climate change, agriculture, healthcare, and industrial development.

4. Encourage Global Collaboration: Foster international partnerships among academia, industry, and governments to ensure that the benefits of quantum technologies are shared globally, with a focus on reducing inequalities in education and research.

5. Highlight Scientific and Cultural Significance: Celebrate the history of quantum science as part of our shared cultural heritage and showcase its impact on art, culture, and philosophical perspectives.

6. Model Scientific Conduct: Promote the ideals of scientific inquiry, including open science practices, international collaboration, and the free sharing of information, to inspire future generations of scientists.

7. Engage with the Public: Organize events, workshops, and interactive exhibitions to make quantum science accessible and engaging to diverse audiences, bridging the gap between complex scientific concepts and public understanding.

Through these objectives, IYQ 2025 aims to celebrate the achievements of quantum science over the past century and to inspire a future where quantum technologies play a pivotal role in addressing global challenges and enhancing the quality of life worldwide.

Some Applications of Quantum Science in Everyday Life

Quantum science finds wide applications in practically all aspects of everyday life. Here are some of the more distinctive ones:

  • Micro- and nano- electronic devices which operate based on quantum mechanics principles like electron tunneling.
  • Lasers and a wide range of related optical technologies.
  • Nuclear Magnetic Resonance (NMR), which is the foundation for medical imaging.
  • Light-emitting diodes (LEDs) and organic LEDs (OLEDs) in televisions, smartphones, and other displays operating on quantum principles.
  • GPS and Atomic Clocks which use quantum mechanics to keep extremely precise time for navigation and other applications.
  • Superconductors, which rely on quantum physics, are used in Maglev trains, powerful electromagnets, and particle accelerators.
  • While still developing, quantum computers promise breakthroughs in materials science, medicine, and complex simulations by leveraging principles of superposition and entanglement.
  • Solar Cells - Quantum mechanics explains how light is converted into electricity in solar panels, improving efficiency in renewable energy.

These applications show how deeply quantum science is embedded in daily life and technology, even if we don’t always notice it.

Quantum Theoretical Physics

Now, back to the main theme of quantum theoretical physics and its pioneers. Both as a student and later as a teacher of collegiate physics, I feel justified in venturing to write about this topic in a series of articles spread over a few months this year.  The subject matter is such that the use of some mathematical expressions and equations becomes inevitable to convey the gist of it, and they should not be an impediment to grasp the essence of the article as a whole, especially from a historical perspective.

First, let us examine the circumstances that led to a drastic change in our understanding of how nature operates, in the early twentieth century.

Physics in Crisis

At the turn of the twentieth century, the world of physics was in turmoil under the dark clouds of conflict between experiments and theory, facing a series of crises, one of which was the inability to account for the distribution of energy observed in the spectrum of blackbody radiation. A blackbody is one that ideally absorbs all the energy incident on it in the form of electromagnetic radiation such as light, x-rays, microwaves, etc., and exhibits distinctive characteristics in the energy radiated by it when heated. The prevailing theory led to an anomalous situation called the ultraviolet catastrophe! The German physicist Max Planck overcame this with his energy quantization hypothesis as elaborated later.  This, and Einstein’s theory of the photoelectric effect, together marked the birth of the Quantum Theory.

[Another crisis of the time, the inability to detect any difference in the speed of light due to the Earth’s motion through the hypothetical aether permeating all space, was also resolved by Einstein, with his Theory of Relativity that led to equally revolutionary developments.]

Annus Mirabilis

Science historians often refer to 1905 as Annus Mirabilis (the ‘Miraculous Year’), marking the birth of the greatest revolution in modern physics, with the publication of four seminal scientific papers by Albert Einstein in the German science journal, Annalen der Physik. They brought about a radical transformation in our understanding of the most fundamental physical concepts such as matter, energy, space, time, charge, spin, etc. One of these papers, on the interpretation of the photoelectric effect, based partly on the earlier concept of the emission or absorption of energy in discrete steps (called quanta) first introduced by Max Planck in 1900, was to lay the foundation for the quantum revolution that is now in focus in IYQ2025.  While Planck’s photon theory assumed quantization only in the processes of emission and absorption of energy, Einstein’s explanation of the photoelectric effect had gone further by postulating even the very existence of energy in quantized form. This was a huge step forward, placing the quantum mechanics that followed on a sure footing.

Dramatis Personae

Quantum theory, and the new quantum mechanics that followed it circa 1925, were the result of key contributions from a large number of outstanding personalities*, most notably the following, roughly in chronological order:  

  1. Max Planck (1858 – 1947)
  2. Albert Einstein (1879–1955)
  3. Niels Bohr (1885–1962)
  4. Louis de Broglie (1892 – 1987)
  5. Werner Heisenberg (1901–1976)
  6. Erwin Schrödinger (1887–1961)
  7. Wolfgang Pauli (1900 – 1958)
  8. Paul Dirac (1902–1984)
  9. Max Born (1882–1970)
  10. Richard Feynman (1918–1988)

[*Some notable omissions: Satyendra Nath Bose, Arnold Sommerfeld, Enrico Fermi, John von Neumann, John Bell, Murray Gell-Mann, Steven Weinberg… and more.]

With some aid from AI apps DeepSeek and ChatGPT, their lives and contributions are probed, narrated and discussed below in an effort to weave a story of quantum theoretical physics in the twentieth century.

The story begins with the failure of classical theory to account for the observed properties of blackbody radiation and the resolution of the problem by Max Planck, ushering in the quantum revolution that finds an echo this year.

Max Planck (1858 – 1947)

and the birth of Quantum Physics 

Max Planck, a name synonymous with the birth of quantum theory, stands as one of the pioneering physicists of the 20th century. His groundbreaking work not only revolutionized our understanding of the physical world but also laid the foundation for modern physics.

Blackbody Radiation

The study of black body radiation and the development of Planck's formula for the distribution of energy in its spectrum represent a cornerstone in the history of physics. This work not only resolved a major theoretical problem at the turn of the 20th century but also laid the foundation for quantum mechanics that followed. The interplay between experimental observations and theoretical insights was critical in deriving Planck's formula, which describes the energy distribution of black body radiation as a function of wavelength and temperature (see illustration below). It represents years of hard work by experimenters in different countries, mainly in Europe.

 

Ultraviolet Catastrophe

A black body is an idealized object that absorbs all incident electromagnetic radiation and emits energy in a characteristic spectrum that depends solely on its temperature. By the late 19th century, experimenters had meticulously measured the spectral distribution of black body radiation, revealing that the intensity of emitted radiation increased with temperature and peaked at a wavelength inversely proportional to the temperature (Wien's displacement law). However, classical physics struggled and failed to explain the full spectrum of black body radiation.

The Rayleigh-Jeans law, derived from classical thermodynamics and electromagnetism, successfully described the intensity of radiation at long wavelengths but failed catastrophically at short wavelengths. According to this law, the energy density of radiation would increase rapidly and without limit as the wavelength decreased, leading to an anomalous situation dubbed as the "ultraviolet catastrophe." (see illustration below). This discrepancy between theory and experiment highlighted the limitations of classical physics and demanded a new theoretical framework. 


Planck's Quantum Hypothesis

In 1900, Max Planck proposed a revolutionary solution to this problem. By introducing the concept of quantized energy, Planck derived a formula that accurately matched the experimental data across all wavelengths. Planck's formula for the spectral energy density E (λ, T) is given by:

Planck's key insight was to assume that the energy of the oscillators in the black body walls could only take on discrete values, proportional to an integer multiple of a fundamental unit hν, where ν is the frequency of the oscillator. 

This is nearly as famous as Einstein’s E = mc2

This quantization of energy was a radical departure from classical physics, which assumed energy could vary continuously.

Experimental Validation

Planck's formula was immediately successful in explaining the observed black body spectrum. Experimentalists had already gathered precise data on the intensity of radiation at different wavelengths and temperatures, and Planck's theoretical predictions matched these observations with remarkable accuracy. For example, the formula correctly predicted the peak wavelength of emission and the fall-off at both shorter and longer wavelengths, resolving the ultraviolet catastrophe triumphantly.

The experimental work of physicists like Wilhelm Wien, Otto Lummer, and Ernst Pringsheim played a crucial role in validating Planck's theory. Their meticulous measurements of black body radiation provided the empirical foundation that guided Planck's theoretical efforts.

Theoretical Implications

Planck's work had profound implications for physics. The introduction of quantized energy levels challenged the classical view of continuous energy exchange and paved the way for the development of quantum mechanics. Albert Einstein later extended Planck's ideas to explain the photoelectric effect, further solidifying the concept of quantization.

Planck's constant h, a fundamental parameter in his formula, became a cornerstone of quantum theory. Its small value 6.626 x 10-34 Js explains why quantum effects are not observed in everyday macroscopic phenomena but are critical at atomic and subatomic scales.

The derivation of Planck's formula for black body radiation exemplifies the synergy between experimental and theoretical physics. Experimental observations revealed the limitations of classical theories, while Planck's bold theoretical hypothesis provided a new framework that resolved these discrepancies. This work not only explained black body radiation but also revolutionized our understanding of energy and matter, marking the birth of a new branch of physics. Planck's formula remains a testament to the power of combining empirical evidence with innovative theoretical thinking.

Planck - Early Life and Education

Max Karl Ernst Ludwig Planck was born on April 23, 1858, in Kiel, Germany, into an intellectual and culturally rich family. His father, Johann Julius Wilhelm Planck, was a law professor. From an early age, Planck exhibited a keen interest in mathematics and science, excelling in his studies. He attended the Maximilians Gymnasium in Munich, where he developed a strong foundation in classical education. In 1874, Planck enrolled at the University of Munich to study physics. Despite being advised against pursuing theoretical physics—a field considered to have limited prospects at the time—Planck was undeterred. He later transferred to the University of Berlin, where he studied under renowned physicists Hermann von Helmholtz and Gustav Kirchhoff. Planck completed his doctoral dissertation in 1879 on the second law of thermodynamics, a topic that would remain central to his scientific career.

Academic Career and Early Work

After earning his doctorate, Planck began his academic career, teaching at the University of Munich and later at the University of Kiel. In 1889, he succeeded Kirchhoff as a professor at the prestigious University of Berlin, where he spent the majority of his career. Planck’s early work focused on thermodynamics, particularly the study of entropy and the behavior of heat in physical systems. His research during this period laid the groundwork for his later revolutionary discoveries.

This hypothesis marked the birth of quantum theory, a radical departure from classical physics. Although Planck himself was initially hesitant about the implications of his discovery, it paved the way for a new understanding of atomic and subatomic processes. His work inspired a generation of physicists, including Albert Einstein, Niels Bohr, and Werner Heisenberg, who further developed quantum mechanics.

The Reluctant Revolutionary

Although Max Planck is considered the father of quantum theory, he was initially reluctant to accept its deeper implications. His reservations about quantum theory included the following:      

  • Introduction of the Quantum Hypothesis as a Mathematical Trick: Planck introduced the idea of quantized energy (E = nhν, where n is an integer) to solve the black-body radiation problem, but he saw it as a mathematical convenience rather than a fundamental shift in physics. He hoped that a more classical explanation would eventually emerge.
  • Discomfort with Discontinuity in Energy: Classical physics assumed that energy was continuous, but quantum theory introduced discrete energy levels. Planck struggled with the idea that nature could fundamentally be discrete rather than continuous.
  • Skepticism Toward the Broader Implications of Quantum Theory: While Planck accepted his quantum hypothesis for black-body radiation, he was skeptical of how it was extended by Einstein (in the photoelectric effect) and later by Bohr (in atomic structure). He initially resisted the idea that quantization applied universally.
  • Hope for a Classical Explanation: Planck believed that quantum theory was temporary and that future developments in classical physics might restore continuity. This was also Einstein’s stand as we shall see later. He spent years searching for a derivation of his radiation law that did not require quantization.
  • Discomfort with Probabilistic Interpretations: Later developments in quantum mechanics, especially Heisenberg’s uncertainty principle and the probabilistic interpretation by Born and Bohr, were far from Planck’s original vision. He was uneasy about abandoning strict determinism.

Despite these reservations, Planck’s work laid the foundation for quantum mechanics, even though he, like his contemporary Einstein, never fully embraced its later developments.

Recognition and Later Career

Planck’s contributions to physics earned him widespread recognition. In 1918, he was awarded the Nobel Prize in Physics for his discovery of energy quanta. Despite the acclaim, Planck remained a humble and dedicated scientist, continuing his research and teaching throughout his life. He served as the president of the Kaiser Wilhelm Society (now the Max Planck Society) from 1930 to 1937, promoting scientific research in Germany.

A galaxy of Nobel Laureates: From left to right: Walther Nernst, Albert Einstein, Max Planck, Robert Millikan (from the USA), and Max von Laue (hosted by Laue in 1931)

Planck’s later years were marked by personal tragedy and the challenges of living through two World Wars. His first wife, Marie Merck, died in 1909, and his eldest son, Karl, was killed in action during World War I. During World War II, Planck’s home in Berlin was destroyed by Allied bombing, and his second son, Erwin, was executed by the Nazis for his involvement in the failed plot to assassinate Adolf Hitler in 1944. Despite these hardships, Planck remained committed to his scientific work and the pursuit of knowledge. 

Later years - a picture of solitude

Planck’s Legacy

Max Planck’s legacy is immense. His introduction of the quantum hypothesis revolutionized physics and led to the development of quantum mechanics, which underpins much of modern technology, from semiconductors to lasers. The Max Planck Society, established in his honor, continues to be one of the world’s leading research organizations, fostering innovation and discovery across a wide range of scientific disciplines.

Planck’s life and work exemplify the power of curiosity, perseverance, and intellectual courage. This profound humility and recognition of the limits of human understanding underscore Planck’s enduring influence on science and philosophy. 


“The Max Planck Society is Germany's most successful research organization. With 31 Nobel Laureates among the ranks of its scientists, it is on equal footing with the best and most prestigious research institutions worldwide.”

Max Planck Institute for Multidisciplinary Sciences. At the Institute, researchers explore scientific issues ranging from physics and chemistry to structural and cell biology, neuroscience and biomedical research.

The Planck space observatory operated by the European Space Agency (ESA) from 2009 to 2013. It was an ambitious project that aimed to map the anisotropies of the cosmic microwave background (CMB) at microwave and infrared frequencies, with profound impact on Cosmology.

 

Point to ponder

Students of science and philosophy may like to debate a statement attributed to Planck:

"Science cannot solve the ultimate mystery of nature. And that is because, in the last analysis, we ourselves are a part of the mystery that we are trying to solve."

 

Acknowledgement

This article (as also the ones to follow on this theme) has been inspired by Dr A G Kulkarni of Bangalore who is himself actively involved in the promotion and advocacy of IYQ25 and other initiatives.